Enhanced coagulation for removal of dissolved organic nitrogen in water: A review

Wastewater treatment plants (WWTPs) meeting strict nutrient discharge regulations typically effectively remove inorganic nitrogen, leaving dissolved organic nitrogen (DON) as the main component of total nitrogen in the effluent. DON in treated effluent from both WWTPs and drinking water treatment plants (DWTPs) has the potential to induce eutrophication and contribute to the formation of nitrogenous disinfection byproducts (N-DBP). While numerous studies have investigated DON in different water sources, a limited number of studies have focused on its removal through enhanced coagulation. The variable removal efficiencies of dissolved organic carbon (DOC) and DON in treatment processes highlight the need for comprehensive research on enhanced coagulation for DON removal. Enhanced coagulation is a viable option for DON removal, but underlying mechanisms and influencing factors are still being actively researched. The effectiveness of enhanced coagulation depends on DON characteristics and coagulant properties, but knowledge gaps remain regarding their influence on treatment. DON is a complex mixture of compounds, with only a small fraction identified, such as proteins, degraded amino acids, urea, chelating agents, humic substances, and soluble microbial products. Understanding molecular-level characteristics of DON is crucial for identifying unknown compounds and understanding its fate and transformation during treatment processes. This review identifies knowledge gaps regarding enhanced coagulation process for DON removal, including the role of coagulant aids, novel coagulants, and pretreatment options. It discusses DON characteristics, removal mechanisms, and molecular-level transformation of DON during enhanced coagulation. Addressing these gaps can lead to process optimization, promote efficient DON removal, and facilitate safe water production.