Sampling strategy, quantification, characterization and hazard potential assessment of greywater from ships in the...

Ship-generated greywater contains a variety of pollutants which, through various pathways, usually are discharged into the sea. To understand the seasonal variation in greywater volumes, the contaminant concentrations in, and the potential hazard of, ship-generated greywater streams, a four-phase strategy for sampling, characterization and hazard assessment of greywater was developed and implemented. Eight greywater streams, sampled from five ships, were characterized for selected pollutants. The metals Zn, Cu, Mn and the metalloid, As, collectively contributed 98 % to the Hazard Index. Laundry greywater had the highest average concentration of phosphorus (42 mg/l) while galley greywater had the highest average concentration of nitrogen (30 mg/l). The geometric means of COD-Cr, BOD₅, TSS and P exceeded the IMO resolution MEPC 227(64) guideline values for sewage effluent from Advanced Wastewater Treatment Plants. The results establish the basis for and contribute to discussions on, the optimization of ship-generated greywater management and the establishment of potential regulatory strategies in the Baltic Region.