Simple and low-cost colorimetric method for quantification of surface oxygen vacancy in zinc oxide
Mei Li1, Ling Zhang1, Wei Liu1
1Key Laboratory of Applied Surface and Colloid Chemistry, Ministry of Education, Key Laboratory of Analytical Chemistry for Life Science of Shaanxi Province, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi'an, 710062, China.
Abstract:
Zinc oxide (ZnO) nanoparticles with surface oxygen vacancy (OV) was found to catalyze the colorimetric reaction of 3,3',5,5'-tetramethylbenzidine (TMB)-H2O2, and the absorbance of this TMB-H2O2-ZnO system was strongly dependent the OV concentration on surface of ZnO. By taking advantage of this phenomenon, one colorimetric method was proposed for quantifying surface OV in ZnO. The surface OV amount obtained through this colorimetric method matched well with that obtained through X-ray photoelectron spectroscopy (XPS). This colorimetric method doesn't need any advanced instruments, and can be completed in any an ordinary laboratory. This colorimetric method for detecting surface OV amount was simple, rapid (about 15 min) and low-cost.
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