Enhancing Hybrid Photovoltaic-Thermal System Efficiency with Boron Dipyrromethene Dyes

A library of boron dipyrromethene (BODIPY) compounds was studied to assess their efficacy as components of a working liquid in hybrid photovoltaic-thermal (PVT) systems. Two series of BODIPY dyes were investigated: series I included alkylBODIPYs with varying substitution patterns, while series II included 1,3,5,7-tetramethyl-substituted BODIPYs featuring electron-rich aromatic groups in the meso position, such as naphthalene, anthracene, and carbazole. Series II dyes were designed to exhibit luminescence downshifting due to enhanced UV absorption (300-400 nm) and excited-state energy transfer, leading to visible-region fluorescence under UV excitation. Samples of PVT liquids based on decalin and containing each individual BODIPY dye were tested on a standard a-Si solar cell to evaluate their impact on solar energy conversion efficiency. The thermal behavior of the working liquid and the cell during the illumination cycle was monitored, alongside the cell's electrical characteristics. Energy conversion pathways and the overall effects of the dyes on the system performance were scrutinized. Results indicated that all BODIPY dyes enhanced both the electrical conversion efficiency (up to 2.41% increase) and thermal energy generation (up to 6.87%) compared to the solvent alone. These findings highlight the potential of BODIPY dyes to significantly improve the performance of PVT systems.