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Antifungal Agents01:15

Antifungal Agents

Amphotericin B is a broad-spectrum antifungal agent that exploits structural differences between fungal and mammalian cell membranes. Its amphipathic structure—featuring a hydrophobic polyene-lactone ring and a hydrophilic region containing mycosamine and carboxylic acid groups—enables selective binding to ergosterol, a sterol predominantly found in fungal plasma membranes. This selective interaction underlies the drug’s antifungal activity, although weak binding to cholesterol contributes to...

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Biomimetic Multi-Interface Design of Raspberry-like Absorbent: Gd-doped FeNi3@Covalent Organic Framework Derivatives

Ruizhe Hu1, Xue He1, Yuqi Luo1

  • 1Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle, School of Environmental and Chemical Engineering, Nanchang Hangkong University, Nanchang, 330063, P. R. China.

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Summary

This study introduces a novel raspberry-like electromagnetic wave absorber (EMWA) using a biomimetic design. The material demonstrates excellent absorption performance with a wide effective absorption bandwidth (EAB) and significant radar cross-section reduction.

Keywords:
COF derivativesGd‐doped FeNi3biomimetic multi‐interface designselectromagnetic wave absorptionmicroscale magnetic interaction

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Electromagnetics

Background:

  • Effective electromagnetic wave absorption (EMWA) and broad effective absorption bandwidth (EAB) are crucial for advanced materials.
  • Structural design and interface regulation are key strategies to enhance EMWA properties.

Purpose of the Study:

  • To develop a novel, high-performance EMWA material with a biomimetic design.
  • To investigate the synergistic dielectric-magnetic properties of the fabricated composite for optimized EM wave attenuation.

Main Methods:

  • Fabrication of a raspberry-like absorbent using a monomer-mediated strategy for covalent organic framework (COF) wrapping of Gd-doped FeNi3 (GFN) nanoparticles.
  • Construction of a dielectric-magnetic synergistic system with COF-derived nitrogen-doped porous carbon (NPC) shell and GFN core.
  • Tuning electromagnetic parameters by adjusting GFN and NPC proportions and utilizing off-axis electron holography to analyze EM wave loss mechanisms.

Main Results:

  • The GFN@NPC composites exhibited tunable electromagnetic parameters and broad EMWA performance.
  • An effective absorption bandwidth (EAB) up to 6.0 GHz was achieved for all composites.
  • The GFN@NPC-2 sample showed a minimum reflection loss (RLmin) of -69.6 dB and a maximum radar cross-section (RCS) reduction of 29.75 dB·m².
  • A multi-layer gradient structure achieved an ultra-wide EAB of 12.24 GHz through metamaterial simulation.

Conclusions:

  • The study presents a novel bio-inspired design strategy for high-performance EMWA materials.
  • The fabricated GFN@NPC composites demonstrate significant potential for electromagnetic wave absorption applications.
  • Interface polarization and microscale magnetic interactions play a critical role in the EM wave loss mechanism.