Related Experiment Video
Updated: Jun 11, 2025

Integrating a Triplet-triplet Annihilation Up-conversion System to Enhance Dye-sensitized Solar Cell Response to Sub-bandgap Light
Published on: September 12, 2014
Asymmetric BODIPY Dyes Enabling Triplet-Triplet Annihilation Upconversion
Daniel Álvarez-Gutiérrez1, Diego Sampedro2, M Consuelo Jiménez1
1Departamento de Química, Universitat Politècnica de València, Camino de Vera S/N, 46022 Valencia, Spain.
Abstract:
The construction of triplet-triplet annihilation upconversion (TTA-UC) systems with upconversion (UC) emission efficiency at low power densities is still under continuing exploration. From an environmental point of view, the utilization of purely organic pairs is more beneficial than the involvement of transition-metal complexes. In this context, 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes, which can be found in a wide range of applications, have been previously used as suitable sensitizers in TTA-UC systems. The versatility of these scaffolds makes them magnificent objectives for designing and synthesizing potential entities with different target abilities. Herein, we prepared several asymmetric BODIPY dyes with excellent optical properties to be applied to a bimolecular TTA-UC system. In the presence of 2,5,8,11-tetra-tert-butylperylene (TBPe) as a suitable annihilator, a green-to-blue light conversion was clearly observed by means of detailed spectroscopic investigations. The results revealed a high UC emission efficiency (ηUC) of ∼8%, together with a low threshold intensity (I th) of ∼40-50 mW/cm2. All data indicated that these asymmetric BODIPY dyes were ideal sensitizers for TTA-UC, providing a particular design for further investigations.
Related Concept Videos
Interpreting ¹H NMR Signal Splitting: The (n + 1) Rule
¹H NMR: Complex Splitting
Splitting diagrams or splitting tree diagrams are routinely used to depict such complex couplings. While drawing splitting diagrams, the splitting with the larger coupling constant is usually applied...
¹H NMR: Pople Notation
A proton...
¹H NMR: Interpreting Distorted and Overlapping Signals
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are...
Photochemical Electrocyclic Reactions: Stereochemistry
Selection Rules: Photochemical Activation

