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Bonding in Metals02:32

Bonding in Metals

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Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
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Complexation Equilibria: Factors Influencing Stability of Complexes01:09

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In complexation reactions, metal cations are the electron pair acceptors, and the ligands are the electron pair donors. The stability of the metal complexes depends primarily on the complexing ability of the central metal ion and the nature of the ligands. Generally, the complexing ability of the metal ion depends on the size and charge of the ion. As the metal ion size increases, the stability of the metal complexes decreases, provided that the valency of the metal ion and the ligands remain...
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

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Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
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Atomic Nuclei: Nuclear Relaxation Processes01:23

Atomic Nuclei: Nuclear Relaxation Processes

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In the absence of an external magnetic field, nuclear spin states are degenerate and randomly oriented. When a magnetic field is applied, the spins begin to precess and orient themselves along (lower energy) or against (higher energy) the direction of the field. At equilibrium, a slight excess population of spins exists in the lower energy state. Because the direction of the magnetic field is fixed as the z-axis,  the precessing magnetic moments are randomly oriented around the z-axis.
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Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
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Related Experiment Video

Updated: Jun 11, 2025

Visualizing Uniaxial-strain Manipulation of Antiferromagnetic Domains in Fe1+YTe Using a Spin-polarized Scanning Tunneling Microscope
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Gentle tension stabilizes atomically thin metallenes.

Kameyab Raza Abidi1, Pekka Koskinen1

  • 1Nanoscience Center, Department of Physics, University of Jyväskylä, 40014 Jyväskylä, Finland. pekka.j.koskinen@jyu.fi.

Nanoscale
|October 7, 2024
PubMed
Summary
This summary is machine-generated.

This study reveals that crystalline metallenes (2D materials) are best stabilized under tensile strain and low atomic density, challenging previous structural assumptions for synthesis. This finding offers new strategies for creating stable 2D metallene materials.

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Nanotechnology

Background:

  • Metallenes are atomically thin 2D materials without bulk layered structures.
  • Stabilizing metallenes is challenging due to isotropic metallic bonding, hindering direct comparison with theoretical predictions.

Purpose of the Study:

  • To explore the energetic and dynamic stability of 45 metallenes across six lattice types and varying densities.
  • To propose a new paradigm for understanding and stabilizing crystalline metallenes.

Main Methods:

  • Utilized density-functional theory (DFT) calculations.
  • Investigated 45 metallenes across six crystalline lattices (honeycomb, square, hexagonal, and buckled variants).
  • Analyzed stability at varying atomic densities and under tensile strain.

Main Results:

  • Identified 128 dynamically stable crystalline lattices out of 270 configurations, predominantly under tensile strain and at sporadic densities.
  • Found that energy minima often led to dynamic instability, amorphization, and loss of planarity.
  • Proposed that crystalline metallenes are yielding membranes, not fixed structures.

Conclusions:

  • Crystalline metallenes exhibit enhanced stability under tensile strain and low atomic density.
  • A novel paradigm viewing metallenes as yielding membranes is suggested.
  • This approach may guide the synthesis of larger, more stable metallene samples for applications in plasmonics, optics, and catalysis.