Understanding the Adsorption Kinetics of Acetone in Humid Activated Carbons: Perspectives from...

The presence of water vapor influences the adsorption equilibrium and kinetics of volatile organic compounds (VOCs) in porous materials. By combination of breakthrough experiments and molecular simulations, the competitive adsorption mechanisms of water vapor and acetone on activated carbon with different textures and surface chemical properties at different humidity levels were investigated. Adsorption capacity decreases with increasing relative humidity owing to the formation of preferential adsorption sites between water and the activated carbon surface, while the adsorption rate initially increases and then decreases with increasing relative humidity. Experimental and simulation results revealed that the existence of a small amount of water changed the pore size distributions of activated carbon, thereby promoting the diffusion of acetone molecules. As the relative humidity increased, a portion of the acetone dissolved in water, resulting in a reduction in the adsorption rate. The response of different functional groups to relative humidity was further clarified by molecular simulation. Activated carbons with a high electrostatic interaction with acetone were less affected by humidity and thus exhibit greater potential as adsorbents.