Corrosion Inhibition of Carbon Steel in Neutral Chloride Solutions Using Salts of Primary Bile Acids

Due to growing environmental concerns and regulatory pressures, the demand for environmentally friendly corrosion inhibitors has increased. Biosurfactants are biodegradable and have a low toxicity. However, very few studies have reported on their potential use as corrosion inhibitors. The present study reports the novel application of two bile salts (sodium cholate NaC and sodium chenodeoxycholate NaCDC) as environmentally friendly corrosion inhibitors for carbon steel in a neutral 20 mM NaCl solution. The results of potentiodynamic polarization and electrochemical impedance measurements showed that when added at a concentration of 5 mM, the corrosion inhibition efficiencies of NaC and NaCDC were about 60% and 85%, respectively. The poor inhibitory character of NaC was confirmed by XPS analysis, revealing the formation of oxidative corrosion products on the steel surface. For the steel sample immersed in the solution containing NaCDC, the XPS measurements showed clear evidence of the presence of an organic layer and a passive oxide film on the steel surface. While the steroidal skeleton of NaC is characterized by marked biplanarity (considering its hydrophobic and hydrophilic faces), NaCDC features a steroidal ring with a hydrophilic edge (it does not exhibit biplanarity). Thus, the self-assembly and adsorption behavior of these bile salts on the steel surface are different, leading in the case of NaCDC to form a densely packed protective organic layer.