Two-dimensional viologen-based lanthanide coordination polymers as multi-stimuli responsive materials to light and
Hao Wang1, Xiao-Han Sun1, Tian-Tian Wang1
1Key Laboratory of Functional Inorganic Material Chemistry Ministry of Education, School of Chemistry and Material Science Heilongjiang University, 74 Xuefu Road, Harbin 150080, P. R. China. wenbinsun@126.com.
Abstract:
Integrating multi-stimuli response properties in one molecule is challenging. This study presents two 2D polymers, [(Bpydp)Ln(H2O)(BDC)]·NO3·2H2O (Ln = Eu(1), Tb(2)), exhibiting rapid photo-responsiveness and the ability to detect specific small-molecule amines. In particular, complex 1 combines the functions of inkless printing, amine detection, anti-counterfeiting, and fluorescence recognition.
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