In Situ Stimulus Response Study on the Acetylene/Ethylene Purification Process in MOFs

Efficient removal of acetylene (C₂H₂) impurities from polymer-grade ethylene (C₂H₄) in a simple, clean manner remains a challenging goal in industry. The use of porous materials such as metal-organic frameworks (MOFs) is promising for this aim but the acquisition of high purification performance is still hindered by few knowledge on the purification process because the previous conclusions were derived basically from the non-breakthrough tests or ignored the influence of structural difference (crystal structure, morphology, or defect). Here we propose an unprecedented in situ stimulus response strategy to minimize the influence of structural difference, obtain the gas-loading crystal structures of the same MOF before and after light or heat stimulation, directly observe the evolution of pore charge distribution and pore⋅⋅⋅gas interactions under light/heat induction, and finally summarizes the favorable structure for highly efficient purification of C₂H₄. This study opens a new route to understand the relationship between the structure and separation performance for porous materials.