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Updated: Jun 10, 2025

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
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Published on: July 30, 2017

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Experimental Evidence for Zerovalent Pd(NHC) as a Competent Catalyst in C-N Cross-Coupling (NHC = DiMeIHeptCl)

Volodymyr Semeniuchenko1,2, Sepideh Sharif3, Neha Rana3

  • 1Centre for Catalysis Research and Innovation (CCRI), Department of Chemistry and Biomolecular Sciences, University of Ottawa, Ottawa, Ontario K1N 6N5, Canada.

Journal of the American Chemical Society
|October 10, 2024
PubMed
Summary

The novel DiMeIHeptCl ligand stabilizes key palladium intermediates for C-N cross-coupling reactions. This research details the isolation and characterization of these stable palladium complexes, advancing catalytic chemistry.

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