Phase-separated structures of tunable thermoresponsive and matrix polymers for large-scale temperature monitoring
Risako Shibata1, Satoru Matsuda2, Hirofumi Kawakubo2
1Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522, Japan. oakiyuya@applc.keio.ac.jp.
Abstract:
Temperature monitoring is significant and fundamental in the fields of healthcare and medicine. In surgery, ultrasonic cutting devices are used for cutting, coagulation, and hemostasis. However, surgeons are concerned about the collateral thermal damages. For example, due to the limited space during endoscopic surgery, thermal damage is caused by touching the surrounding tissues of the targeted organ with the heated shaft of the ultrasonic cutting device. The present work exhibits thermoresponsive and reversible color-change coatings for temperature-distribution imaging. The phase-separated structures of the layered conjugated and matrix polymers enable both the tuned thermoresponsivity and large-scale coating. Layered polydiacetylene (PDA) with intercalated guests exhibits reversible and thermoresponsive gradual color changes from blue to red. A matrix polymer facilitates formation of the phase-separated layered PDA and large-scale coating. Spraying the precursor solution containing the diacetylene monomer, guest molecule, and matrix polymer provides the self-organized large-scale coatings on substrates. The temperature distribution on the shaft of an ultrasonic cutting device is monitored using the coatings. The phase-separated structure of thermoresponsive and matrix polymers can be applied to tunable temperature monitoring in a variety of fields.
