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Study on the Suppression of Vitrinite Reflectance: A Thermal Simulation Experiment
Hui Zhang1,2,3, Weibo Zhao1,3, Huaichang Wang1,3
1Institute of Exploration, Development and Research, PetroChina Company Limited Changqing, Oilfield Branch, Xi'an 710018, China.
ACS Omega
|October 14, 2024
Summary
Hydrocarbon generation and overpressure suppress vitrinite reflectance (R0) during thermal evolution. This study reveals hydrocarbon impregnation and pore network retention of volatiles cause anomalous R0 values in source rocks.
Area of Science:
- Geochemistry
- Organic Petrology
- Sedimentary Basin Analysis
Background:
- Vitrinite reflectance (R0) is crucial for reconstructing thermal history and assessing source rock maturation.
- Reported suppression of R0 can compromise the accuracy of thermal evolution evaluations.
Purpose of the Study:
- To investigate the impact of hydrocarbon generation on vitrinite reflectance during thermal evolution.
- To elucidate the mechanisms behind R0 suppression in a closed system.
Main Methods:
- Controlled thermal simulation experiments in a closed system.
- Analysis of vitrinite reflectance under varying thermal conditions and kerogen types.
Main Results:
- Hydrocarbon absorption and overpressure were identified as key factors suppressing vitrinite reflectance.
- For R0 values between 0.6% and 2.1%, hydrocarbon impregnation of telocollinite texture by type I kerogen was the primary cause.
- Above 2.1% R0, overpressure emerged as the dominant factor for anomalous reflectance.
Conclusions:
- Hydrocarbon generation significantly influences vitrinite reflectance, leading to suppression.
- The mechanisms of suppression vary with R0 values, involving hydrocarbon impregnation and overpressure.
- Closed-system conditions, retaining volatile products, hinder vitrinite structural reorganization and cause reflectance suppression.
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