Related Experiment Video
Updated: Jun 10, 2025

Evaluating the Electrochemical Properties of Supercapacitors using the Three-Electrode System
Published on: January 7, 2022
Covalent Organic Framework Derived Oxygen/Sulfur-Doped Porous Carbon for Robust High-Capacitance Symmetric
Yue Wang1, Jifan Zhao1, Yuzhu Xing1
1School of Chemical Engineering, University of Science and Technology Liaoning, 185 Qianshan Middle Road, High-Tech Zone, Anshan, Liaoning, 114051, China.
Abstract:
Heteroatom-doped porous carbons (HPCs) have been considered promising electrode materials for supercapacitors due to their improvement of energy density by providing extra pseudocapacity. Covalent organic frameworks (COFs) are obtaining great importance in energy storage because of their designable structure and versatile functionality. Herein, we designed and fabricated oxygen and sulfur dual-doped covalent organic framework (COF) derived HPCs with very high heteroatoms content (up to 25.76 atom%) via a facile coupling reaction. The optimized HPCs exhibit a porous structure with high specific surface area (up to 2835 m2 g-1) along with a high specific capacitance (430 F g-1 at 0.5 A g-1), excellent capacitance retention (96.9 %), and high coulombic efficiency (98.5 %) after 10000 cycles at 5 A g-1. As electrodes for aqueous symmetric supercapacitors, the HPCs exhibits a high energy density of 60 Wh kg-1 at a 250 W kg-1 power density, excellent cycling stability of capacity retention (82.2 %) and a high coulombic efficiency (92.3 %) after 10000 cycles at 10 A g-1, indicating attractive application potential in chemical energy storage. This work establishes a promising strategy for preparation of high heteroatom content HPCs using COFs and demonstrates great potential for energy storage/conversion devices.
More Related Videos
08:59Synthesizing a Gel Polymer Electrolyte for Supercapacitors, Assembling a Supercapacitor Using a Coin Cell, and Measuring Gel Electrolyte Performance
Published on: November 30, 2022
08:42Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
Published on: July 10, 2017
Related Concept Videos
MOS Capacitor
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
Capacitor With A Dielectric
Dielectrics are non-conducting materials with no free or loosely bound electrons. When a dielectric is...
Energy Stored in a Capacitor
Energy Stored in Capacitors
By integrating the equation that relates voltage and current in a capacitor, one can derive an equation for the voltage across the capacitor at any given time. This equation is crucial in understanding and predicting the behavior of capacitors in...
Equivalent Capacitance
Capacitors and Capacitance
When the conductors are two identical parallel plates, it is called a parallel plate capacitor. When battery terminals are...