CuS enabled efficient Fenton-like oxidation of phenylarsonic acid and inorganic arsenic immobilization

Herein, copper sulfide (CuS) was introduced to the Fenton-like (Fe(III)/H₂O₂) system for the efficient removal of phenylarsonic acid (PAA). Results of reactive oxygen and Fe/Cu species showed that CuS preferentially reacted with Fe(III) and H₂O₂ to generate Cu(I) and superoxide anion (•O₂^-). These reductive species could efficiently promote the Fe(III)/Fe(II) and Cu(II)/Cu(I) cycles, and are beneficial to the sequential Fenton reaction to generate •OH. The organoic/inorganic arsenic species detected in the CuS/Fe(III)/H₂O₂ system confirmed that PAA was oxidized by •OH to hydroxylated organoarsenic and phenolic intermediates, which were further mineralized to oxalate and formic acid. Meanwhile, the inorganic As(III)/As(V) released during PAA degradation were efficiently immobilized by CuS. The PAA removal efficiency remained as high as 92.9 % after 5 cycles of the CuS-mediated Fenton-like process. These results demonstrate an innovative method for the treatment of organoarsenic-contaminated water, and provide new insights into the enhanced Fenton-like process utilizing sulfide minerals.