Photoelectrochemical transistors based on semiconducting polymers: an emerging technology for future bioelectronics

In recent years, organic electrochemical transistors (OECTs) have attracted widespread attention due to their significant advantages such as low-voltage operation, biocompatibility, and compatibility with flexible substrates. Organic photoelectrochemical transistors (OPECTs) are OECTs with photoresponse capabilities that achieve photoresponse and signal amplification in a single device, demonstrating tremendous potential in multifunctional optoelectronic devices. In this mini-review, we briefly introduce the channel materials and operation mechanisms of OECTs/OPECTs. Then different types of OPECTs are discussed depending on their device-architecture-related photoresponse generation. Following this, we summarize recent advances in OPECT applications across various fields including biomedical sciences, optoelectronics, and sensor technologies. Finally, we outline the current challenges and explore future research prospects, aiming at extending their further development and applications.