Related Experiment Video
Updated: Jun 10, 2025

Solvent Bonding for Fabrication of PMMA and COP Microfluidic Devices
Published on: January 17, 2017
Antimony centre in three different roles: does donor strength or acceptor ability determine the bonding pattern?
Richard Chlebík1, Csilla Fekete2, Roman Jambor1
1Department of General and Inorganic Chemistry, University of Pardubice, Studentská 573, CZ 532 10 Pardubice, Czech Republic. libor.dostal@upce.cz.
Abstract:
A set of antimony(III) compounds containing a ligand (Ar) with a pendant guanidine function (where Ar = 2-[(Me2N)2CN]C6H4) was prepared and characterized. This includes triorgano-Ar3Sb, diorgano-Ar2SbCl and monoorgano-ArSbCl2 compounds and they were characterized by 1H and 13C NMR spectroscopy and by single-crystal X-ray diffraction analysis (sc-XRD). The coordination capability of Ar3Sb and Ar2SbCl was examined in the reactions with either cis-[PdCl2(CH3CN)2] or PtCl2 and complexes cis-[(κ2-Sb,N-Ar3Sb)MCl2] (M = Pd 1, Pt 2) and [(κ3-N,Sb,N-Ar2SbCl)MCl2] (M = Pd 3, Pt 4) were isolated, while their structures were determined by sc-XRD. Notably, the ligands Ar3Sb and Ar2SbCl exhibit different coordination modes - bidentate and tridentate, respectively - and the antimony exhibits three distinct bonding modes in complexes 1-4, which were also subjected to theoretical studies.
More Related Videos
Related Concept Videos
Ionic Bonding and Electron Transfer
Chemical Bonds
Atoms participate in a chemical bond formation to acquire a completed valence-shell electron configuration similar to that of the noble gas nearest to it in atomic number. Ionic, covalent, and metallic bonds are some of the important types of chemical bonds. Bond energy and bond length determine the strength of a chemical bond.
Types of Chemical Bonds
An ionic bond is formed due to electrostatic attraction between cations and anions. Often, the ions are formed by the transfer of electrons...
Bond Polarity, Dipole Moment, and Percent Ionic Character
Bonding in Metals
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Hybridization of Atomic Orbitals I

