High-Performance Supercapacitive Pressure Sensors via Height-Grading Micro-Domes of Ionic Conductive Elastomer

Soft capacitive sensors present numerous appealing characteristics, including simple structure, low power consumption, and fast response. However, they often suffer from low sensitivity and a limited linear sensing range. Herein, a concept is presented to enhance the sensitivity and linearity of supercapacitive pressure sensors by functionally grading the heights of macrodomes constructed from a highly elastic and ionic conductive elastomer made of poly(vinyl alcohol) and phosphoric acid (PVA/H₃PO₄). The resultant supercapacitive sensors exhibit a high sensitivity (423.42 kPa^-1), wide linear sensing range (0-400 kPa), ultralow limit of detection (0.48 Pa), and high durability (stable signal outputs up to 5000 cycles of loading/unloading). Additionally, the sensors can maintain consistent sensing performance within a temperature range of 25-40 °C. The potential of the sensor in health monitoring is demonstrated through ultrahigh-resolution weight measurement, pulse detection, and respiration monitoring.