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Updated: Jun 9, 2025

In Situ Monitoring of Diffusion of Guest Molecules in Porous Media Using Electron Paramagnetic Resonance Imaging
Published on: September 2, 2016
Real-space diffusion theory from quantum mechanics using analytic continuation
Leonardo Di G Sigalotti1, Otto Rendón1, José-Rubén Luévano1
1Universidad Autónoma Metropolitana, Azcapotzalco Campus, Av. San Pablo 420, Colonia Nueva el Rosario, Alcaldía Azcapotzalco, Mexico City, 02128, Mexico.
A novel time transformation links Brownian motion and quantum mechanics, revealing that probability density and proper time stem from time symmetry breaking. This connection offers classical interpretations for quantum phenomena.
Area of Science:
- Physics
- Quantum Mechanics
- Statistical Mechanics
Background:
- Brownian motion and quantum mechanics are typically described by distinct frameworks.
- Formal analytic continuation and Wick rotation are standard tools in theoretical physics.
- Nelson's stochastic mechanics provides a link between quantum mechanics and Brownian motion.
Purpose of the Study:
- To establish a physical correspondence between Brownian motion and quantum mechanics.
- To explore the implications of a complex conjugate time transformation.
- To provide classical interpretations for quantum mechanical concepts.
Main Methods:
- Formal analytic continuation with a complex conjugate time transformation (replacing Wick rotation).
- Analysis of the invariance of the wave function's square modulus.
- Conforming the Schrödinger equation with a stochastic-mechanical model.
Main Results:
- A direct physical link between quantum mechanics and Brownian motion is established.
- Born's probability density interpretation is connected to proper time via time symmetry breaking.
- Nelson's osmotic velocity and a classical potential interpretation of the quantum phase emerge naturally.
- The Schrödinger equation aligns with stochastic mechanics under the transformation.
Conclusions:
- The study reveals a deep connection between quantum mechanics and classical diffusion processes.
- Time symmetry breaking plays a crucial role in linking microscopic quantum phenomena to macroscopic classical behavior.
- The framework allows for classical interpretations of quantum phase and osmotic velocity.
- Potential for extending the model to anomalous diffusion is discussed.
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