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Glycerol Carbonate as an Emulsifier for Light Crude Oil: Synthesis, Characterization, and Stability Analysis
Ana Beatriz Morales Cepeda1, Elda Elizabeth Villalobos Neri2, Luis Alejandro Macclesh Del Pino Pérez1
1Centro de Investigación en Petroquímica, Tecnológico Nacional de México/Instituto Tecnológico de Cd. Madero, Altamira 89600, Mexico.
Abstract:
This study focuses on the synthesis and application of glycerol carbonate (GC) as an emulsifier for light crude oil. GC was synthesized from glycerol and dimethyl carbonate via transesterification, achieving a 90% yield. Characterization through 1H-NMR, 13C-NMR, and FT-IR confirmed its structure. The emulsification properties of GC were tested by mixing it with light crude oil and water, demonstrating effective emulsification and forming stable emulsions. Stability tests with GC concentrations of 60/40, 70/30, and 80/20 revealed that emulsions remained stable for over 24 h. A particle size analysis indicated that higher GC concentrations produced smaller droplet sizes, enhancing the emulsification efficiency. This study highlights the potential applications of GC in oil spill remediation and enhanced oil recovery, emphasizing its biodegradability and low toxicity as environmental benefits. Overall, GC is presented as an effective and eco-friendly emulsifier for light crude oil, offering stable emulsions and promising industrial applications.
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