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Updated: Jun 9, 2025

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
Published on: August 23, 2018
Exploring the Impact of Water Content in Solvent Systems on Photochemical CO2 Reduction Catalyzed by Ruthenium
Yusuke Kuramochi1,2, Masaya Kamiya2, Hitoshi Ishida2,3
1Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguroku, Tokyo 153-8505, Japan.
Abstract:
To achieve artificial photosynthesis, it is crucial to develop a catalytic system for CO2 reduction using water as the electron source. However, photochemical CO2 reduction by homogeneous molecular catalysts has predominantly been conducted in organic solvents. This study investigates the impact of water content on catalytic activity in photochemical CO2 reduction in N,N-dimethylacetamide (DMA), using [Ru(bpy)3]2+ (bpy: 2,2'-bipyridine) as a photosensitizer, 1-benzyl-1,4-dihydronicotinamide (BNAH) as an electron donor, and two ruthenium diimine carbonyl complexes, [Ru(bpy)2(CO)2]2+ and trans(Cl)-[Ru(Ac-5Bpy-NHMe)(CO)2Cl2] (5Bpy: 5'-amino-2,2'-bipyridine-5-carboxylic acid), as catalysts. Increasing water content significantly decreased CO and formic acid production. The similar rates of decrease for both catalysts suggest that water primarily affects the formation efficiency of free one-electron-reduced [Ru(bpy)3]2+, rather than the intrinsic catalytic activity. The reduction in cage-escape efficiency with higher water content underscores the challenges in replacing organic solvents with water in photochemical CO2 reduction.
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