Shell-induced enhancement of Fenton-like catalytic performance towards advanced oxidation processes: Concept,...

Fenton-like advanced oxidation processes (AOPs) are commonly used to eliminate recalcitrant organic pollutants as they produce highly reactive oxygen species through the reactions between the catalysts and oxidants. Recently, considerable attention has been directed towards shell-structured Fenton-like catalysts that offer high stability, maximum utilization of active sites, and exceptional catalytic performance. In this review, we have introduced the concept of several typical shell-forming architectures (e.g., hollow structure, core-shell structure, yolk-shell structure, particle-in-tube structure, and multi-shelled structure), elucidating their role in promoting Fenton-like reaction catalysis through the nanoconfinement mechanism. In each aspect, the correlation between the shell-induced effects and the Fenton-like catalytic performance is highlighted. Finally, future challenges and opportunities for the development of shell-structured Fenton-like catalysts towards AOPs are presented, offering bright practical application prospects.