Linking Thermal Conductivity to Equations of State Using the Residual Entropy Scaling Theory

In recent years, the application of the residual entropy scaling (RES) method for modeling transport properties has become increasingly prominent. Based on Yang et al. (Ind. Eng. Chem. Res. 2021, 60, 13052) in modeling the thermal conductivity of refrigerants, we present here an RES model that extends Yang et al.'s approach to a wider range of pure fluids and their mixtures. All fluids available in the REFPROP 10.0 software, i.e., those with reference equations of state (EoS), were studied. A total of 71,554 experimental data of 125 pure fluids and 16,702 experimental data of 164 mixtures were collected from approximately 647 references, mainly based on the NIST ThermoData Engine (TDE) database 10.1. As a result, over 68.2% (corresponding to the standard deviation of a normal distribution) of the well-screened experimental data agree with the developed RES model within 3.1% and 4.6% for pure fluids and mixtures, respectively. Comparative analysis against the various models implemented in the REFPROP 10.0 (one of the state-of-the-art software packages for thermophysical property calculations) reveals that our RES model demonstrates analogous statistical agreement with experimental data yet with much fewer parameters. Regarding the average absolute value of the relative deviation (AARD) from experimental values to model predictions, the developed RES model shows a smaller or equal AARD for 74 pure fluids out of 125 and 76 mixtures out of 164. Besides, a detailed examination of the impact of the critical enhancement term on mixture calculations was conducted. To use our model easily, a software package written in Python is provided in the Supporting Information.