Improved Optical Performance Analysis of YAG:Ce, NCS:Sm, and CAO:Mn Phosphors Physically Integrated with...

This research presents a thorough examination of the optical properties and performance enhancement strategies of synthesized phosphors, namely, yttrium aluminum garnet doped with cerium (YAG:Ce), sodium calcium silicate with samarium (NCS:Sm), and calcium aluminate oxide doped with manganese (CAO:Mn). The study delves into the synthesis processes of the phosphors, illumination of the crystal structures, and enhancement of luminescent characteristics. Additionally, the paper extends to the synthesis and analysis of {[Cu(μ₃-dmg)(im)₂]·3H₂O} (PKY159), and the coordination polymer (CP) was added the phosphors to explore a novel approach for enhanced optical performance. When the phosphor composites YAG:Ce, CAO:Mn, and NCS:Sm were made as poly(methyl methacrylate) (PMMA; for homogenization, stabilization) thin films with the coordination polymer PKY159 included, the intensity values increased by 97%, 96%, and 79%, respectively, in comparison to their pristine form. Also, all phosphors along with the PKY159 additive were examined for their decay time kinetics, thermal stabilities, CIE chromaticity coordinates, and quantum efficiencies. The YAG:Ce, NCS:Sm, and CAO:Mn mixes exhibit good thermal stability in addition to internal quantum efficiency (IQE) values that are much higher than the phosphors' additive-free form (95.6%, 66.3%, and 84.6%, respectively). This increase is correlated to an increase in steady-state measurements. These comprehensive analyses contribute valuable insights into the design and optimization of phosphor and coordination polymer blends for improved optical functionality.