Non-target screening reveals 124 PFAS at an AFFF-impacted field site in Germany specified by novel systematic...

The uncontrolled release of aqueous film-forming foam (AFFF) ingredients during a major fire incident in Reilingen, Germany, in 2008 led to significant soil and groundwater contamination. As the identity of fluorochemical surfactants in AFFF are often veiled due to company secrets, it is important to characterize AFFF contaminations and their impact on the environment comprehensively. In this study, we adapted a systematic approach combining a suitable extraction method with liquid chromatography high-resolution quadrupole time-of-flight mass spectrometry (LC-QTOF-MS) for an extensive non-targeted analysis. Our analysis identified 124 per- and polyfluoroalkyl substances (PFAS) from 42 subclasses in the contaminated soil (confidence levels of identification between 1 and 3). Typical for AFFF-impacted field sites, these included anionic, cationic, and zwitterionic substances with perfluoroalkyl chains spanning from 3 to 14 carbon atoms. Furthermore, we identified 1 previously unreported substance, and detected 9 PFAS subclasses for the first time in soil. AFFFs have long been employed to extinguish large hydrocarbon fires, yet their environmental consequences remain a concern. This study sheds light on the complex composition of AFFFs at this particularly contaminated area, emphasizing the necessity for extensive contaminant characterization as sound basis for informed management strategies to mitigate their adverse effects. AFFF PFAS are often named differently in the literature, leading to inconsistency in terminology. To address this issue, we introduced partially new terminology for AFFF-related PFAS to establish consistent terminology, to facilitate communication of identified compounds, and to ensure that the chemical structure can be directly derived from acronyms.