Exploring 1T/2H MoS2 quantum dots modified 2D CoPx nanosheets for efficient electrocatalytic hydrogen evolution
Tian Zhang1, Xiaohui Ren1, Wenzhe Cao1
1The State Key Laboratory of Refractories and Metallurgy, Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education & Hubei Provincial Key Laboratory for New Processes of Ironmaking and Steel Making, Faculty of Materials, Wuhan University of Science and Technology, Wuhan 430081, China.
Abstract:
The exploration of multiphases and 0D/2D heterojunction in transition metal phosphides (TMPs) and transition metal sulfides (TMDs) is of major interest for hydrogen evolution reaction (HER). Herein, a novel combination route where 0D mixed-phased 1T/2H molybdenum sulfide quantum dots (MoS2 QDs) are uniformly anchored on the 2D CoPx nanosheets is developed. MoS2 QDs and CoPx were prepared via hydrothermal method and mixed with different ratios (Mo:Co ratios of 2:1, 1:1, and 1:2) and annealed under different temperatures to modulate their application in acidic HER processes. Specifically, 2Mo/1Co exhibited advanced performance for HER in 0.5 M H2SO4 solution and required 14 mV to deliver 10 mA cm-2 and revealed a descended Tafel slope of 75.42 mV dec-1 with 240 h stability except obvious deactivation. The successful design and construction of 0D/2D mixed-dimensional materials would broaden the application of MoS2 and CoPx for electrocatalytic hydrogen evolution.
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