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Updated: Jun 9, 2025

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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C(sp3)-F Bond Activation by Lewis Base-Boryl Radicals via Concerted Electron-Fluoride Transfer

Xueying Guo1, Yuchen Zhang1, Xiaoyu Lai1

  • 1Key Laboratory of Fluorine and Nitrogen Chemistry and Advanced Materials and Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, 20032, China.

Angewandte Chemie (International Ed. in English)
|October 29, 2024
PubMed

Keywords:
BorylsC−F bond activationDFT calculationIBO analysisRadicals

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