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Updated: Jun 9, 2025

Isotopic Effect in Double Proton Transfer Process of Porphycene Investigated by Enhanced QM/MM Method
Published on: July 19, 2019
β-to-β Singly Linked Subphthalocyanine Dimers with Effective π-Conjugation
Daniel Holgado1, Marta Gómez-Gómez1, Jorge Labella1
1Department of Organic Chemistry, Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049 Madrid, Spain.
Abstract:
In this work, a series of π-conjugated Subphthalocyanine dimers assembled by simple π-bridges were efficiently synthesized through metal-catalyzed reactions. Despite being singly linked, these readily accessible arrays exhibit excellent π-electron communication, significantly perturbing the orbital distribution of conventional SubPcs and inducing notable alterations in their optical properties. The findings presented here demonstrate the potential of SubPcs for constructing curved porphyrin arrays with well-conjugated skeletons and intriguing functionalities.
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