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Related Concept Videos

Ferromagnetism01:31

Ferromagnetism

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Materials like iron, nickel, and cobalt consist of magnetic domains, within which the magnetic dipoles are arranged parallel to each other. The magnetic dipoles are rigidly aligned in the same direction within a domain by quantum mechanical coupling among the atoms. This coupling is so strong that even thermal agitation at room temperature cannot break it. The result is that each domain has a net dipole moment. However, some materials have weaker coupling, and are ferromagnetic at lower...
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Colors and Magnetism03:02

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Color in Coordination Complexes
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
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Mass Analyzers: Common Types01:19

Mass Analyzers: Common Types

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The quadrupole mass analyzer consists of four cylindrical metal rods arranged in a diamond carrying a DC voltage and a radio-frequency AC voltage. The motion of ions through the quadrupole depends on the field strength, causing only ions of a certain m/z to resonate successfully and strike the detector at a given field strength. Though the transmission rate for these analyzers is high, the exact elemental composition of the sample is not determined because of low resolution; however, they are...
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Valence Bond Theory02:42

Valence Bond Theory

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Coordination compounds and complexes exhibit different colors, geometries, and magnetic behavior, depending on the metal atom/ion and ligands from which they are composed. In an attempt to explain the bonding and structure of coordination complexes, Linus Pauling proposed the valence bond theory, or VBT, using the concepts of hybridization and the overlapping of the atomic orbitals. According to VBT, the central metal atom or ion (Lewis acid) hybridizes to provide empty orbitals of suitable...
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Crystal Field Theory - Tetrahedral and Square Planar Complexes02:46

Crystal Field Theory - Tetrahedral and Square Planar Complexes

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Tetrahedral Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
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Crystal Field Theory - Octahedral Complexes02:58

Crystal Field Theory - Octahedral Complexes

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Crystal Field Theory
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
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Measuring Magnetically-Tuned Ferroelectric Polarization in Liquid Crystals
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Composite quadrupole order in ferroic and multiferroic materials.

R Matthias Geilhufe1

  • 1Department of Physics, Chalmers University of Technology, 412 96 Göteborg, Sweden.

Journal of Physics. Condensed Matter : an Institute of Physics Journal
|November 4, 2024
PubMed
Summary
This summary is machine-generated.

Composite orders, previously seen in superconductors, are now proposed for ferroelectric and ferromagnetic materials. This framework explains precursor phenomena and hidden orders in these materials.

Keywords:
composite ordercritical phenomenaferroelectriclandau theorymagnetmultiferroicquadrupole order

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Area of Science:

  • Condensed matter physics
  • Materials science

Background:

  • Composite and intertwined orders formalism successfully explains complex phase diagrams in strongly correlated materials and high-temperature superconductors.
  • Lattice anisotropy plays a crucial role in the emergence of composite orders in ferroic materials.

Purpose of the Study:

  • To propose and investigate the realization of composite orders in ferroelectric and ferromagnetic materials.
  • To demonstrate how composite orders are determined by lattice anisotropy and the easy axis of magnetization or polarization.
  • To extend the composite order formalism to multiferroic materials and explain precursor phenomena.

Main Methods:

  • Theoretical modeling based on the composite and intertwined orders formalism.
  • Analysis of ferroelectric, ferromagnetic, and multiferroic materials considering lattice anisotropy.

Main Results:

  • Composite orders are identified in ferroelectric and ferromagnetic materials above their respective phase transitions.
  • The type of composite order is dictated by the material's easy axis.
  • The formalism naturally incorporates magnetoelectric monopole, toroidal, and quadrupole orders.
  • Composite orders can explain precursor phenomena in incipient ferroic materials.

Conclusions:

  • The composite order formalism provides a unified framework for understanding complex orders in ferroic and multiferroic materials.
  • This approach offers insights into precursor phenomena and potentially hidden orders, aiding in material characterization.