Photocatalytic degradation of organic dyes under sunlight using a mononuclear Zn complex-embedded-functionalized...

In this study, mesoporous materials (MCM-41 and MCM-48) were synthesized and functionalized with an acid group through a post-synthetic modification method. A mononuclear Zn complex [Zn(dmp)Cl₂] (dmp = neocuprine) was also prepared and incorporated into a functionalized mesoporous material. Extensive characterization of the material married was carried out using techniques such as X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) analysis, scanning electron microscopy (SEM), nuclear magnetic resonance (NMR), and Fourier-transform infrared spectroscopy (FT-IR) to evaluate the characteristics of modified materials. The characterization results revealed that the post-synthetic modification did not alter the phase purity, crystallinity, or morphology of the mesoporous materials while confirming the successful grafting of the desired sulphonic acid functionality and Zn complex. The Zn complex-grafted-functionalized mesoporous materials were then assessed for their photo-degradation using methylene blue (MB) and rhodamine B (RB). The results demonstrated exceptional photo-degradation efficiency of the modified materials under sunlight. Within 15 min, 10 mg/ml of dye concentration, and adsorbent dosage 0.15 mg/ml and 0.1 mg/ml, degradation efficiencies of 99% and 92%, were achieved for MB using M-48-S-Zn₁ and M-41-S-Zn₁, respectively. Similarly, 91% and 78% degradation rates were achieved within 30 min for RB using the same materials. The modified mesoporous materials exhibited a remarkable degradation performance even in challenging environments, including highly acidic, basic, and salt-concentrated conditions. This highlights the versatility and robustness of the modified materials in different environmental scenarios.