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  1. Home
  2. Investigation Of The Impact Of Moisture In Various States On The Adsorption Of Ch4, N2, And Co2 By Coal.
  1. Home
  2. Investigation Of The Impact Of Moisture In Various States On The Adsorption Of Ch4, N2, And Co2 By Coal.

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Investigation of the Impact of Moisture in Various States on the Adsorption of CH4, N2, and CO2 by Coal.

Hongmin Yang1,2,3, Xiaotong Lu1, Ningning Kang1

  • 1College of Safety Science and Engineering, Henan Polytechnic University, Jiaozuo, Henan 454003, China.

ACS Omega
|November 11, 2024

View abstract on PubMed

Summary
This summary is machine-generated.

Coal moisture significantly affects gas adsorption. Higher moisture content reduces methane, nitrogen, and carbon dioxide adsorption by altering pore structure and causing competitive adsorption.

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Area of Science:

  • Geochemistry
  • Physical Chemistry
  • Materials Science

Background:

  • Coal is a complex porous material crucial for energy storage and carbon sequestration.
  • Understanding gas adsorption in coal is vital for resource management and environmental applications.
  • The influence of moisture on gas adsorption in coal is a critical factor affecting its storage capacity.

Purpose of the Study:

  • To investigate the impact of varying moisture content and states on the adsorption of methane (CH4), nitrogen (N2), and carbon dioxide (CO2) in coal.
  • To elucidate the adsorption mechanisms of coal moisture and its competitive interactions with gases.
  • To determine the role of pore structure and water condensation in gas adsorption under different moisture conditions.

Main Methods:

  • Isothermal adsorption experiments were conducted on dry and moisture-conditioned coal samples.
  • Adsorption potential theory was applied to analyze competitive adsorption at low moisture content.
  • Liquid nitrogen adsorption and fractal dimension theory were used to characterize pore structure at high moisture content.
  • Main Results:

    • Coal moisture adsorption occurs in four stages: monolayer, multilayer, cluster formation, and condensation.
    • Increasing moisture content progressively reduces the adsorption of CH4, N2, and CO2, with adsorption constants declining.
    • At low moisture, water exhibits higher adsorption potential than CH4, N2, and CO2, indicating competitive adsorption.
    • At high moisture, a fractal dimension close to 3 suggests pore blockage by condensed water, becoming the dominant factor for gas adsorption.

    Conclusions:

    • Coal moisture significantly influences the adsorption of CH4, N2, and CO2 through competitive effects and pore structure modification.
    • The state of coal moisture, from monolayer adsorption to free water condensation, dictates its impact on gas adsorption.
    • The intricate pore structure of coal, especially under high moisture conditions, plays a primary role in gas adsorption by facilitating water condensation and pore blockage.