Immobilization of urea on beads based on OPEFB cellulose-alginate via blending to fabricate sustained release...

Transforming oil palm empty fruit bunches (OPEFB) waste into value-added cellulose as a reinforcement agent for eco-friendly slow-release fertilizer (SRF) composites is a strategy to achieve clean and sustainable production. OPEFB cellulose was isolated by alkalization (10 % w/v NaOH) for 1 h and bleaching (30 % v/v H₂O₂) for 1.5 h. The treatment increased the cellulose content to 80.88 %, reduced the non-cellulosic component, and improved the fiber crystallinity to 58.40 %. The hydrogel composite was cross-linked by blending urea in an OPEFB cellulose fiber (w/w) (0 %, 0.5 %, and 1 %) and sodium alginate (3 % w/w). Then, the wet beads were freeze-dried to fabricate SRF composites. Each material was evenly dispersed in the matrix, had a porous structure, and could bind total nitrogen up to 20.0 %, confirmed by the Kjeldahl method. Adding cellulose increased crystallinity (significant at 1 % w/w cellulose), decreased bulky density (significant at 0.5 % and 1 % w/w cellulose), increased swelling capacity (significant at 0.5 % w/w cellulose), and water-retention capacity. Reinforced composite with 0.5 % (w/w) cellulose released nitrogen into the soil (Fickian diffusion) following the Higuchi model (R² = 0.957) with K = 0.0394 and equilibrium at around t^1/2 = 1.8 h. Changing SRF composite properties are likely related to the porous structure loaded with urea crystals.