Colorimetric ammonia-sensing nanocomposite films based on starch/sodium alginate and Cu-Phe nanorods for smart...

The development of colorimetric ammonia-sensing smart packaging materials with real-time freshness detection ability are crucial for ensuring food safe. This research involved the construction of Cu-based framework (Cu-Phe) nanorods with colorimetric ammonia-sensing ability through an easy-to-perform aqueous solution method, and their subsequent utilization as nano inclusions in starch/sodium alginate (ST/SA) substrate to foster the creation of high-performance smart packaging materials. Research findings revealed that the addition of Cu-Phe nanorods (3, 6, 9 wt%) within ST/SA substrate led to the formation of compatible nanocomposite films with significantly augmented physical performance and functionality. Especially, the film containing 9 wt% Cu-Phe presented the highest tensile strength (30.32 MPa), elongation at break (19.12 %), UV-shielding efficacy (blocking >99 % of UV passage), water vapor barrier effectiveness (1.90 × 10^-6 g/m·h·Pa) and oxygen barrier ability (2.26 × 10^-3 g/m²·s). In addition, the developed ST/SA/Cu-Phe nanocomposite film possessed excellent antibacterial activity (over 99.9 %) against Escherichia coli and Staphylococcus aureus, superior colorimetric ammonia-sensing ability, and long-term colour stability. Also of note, the Cu-Phe added ST/SA nanocomposite film allowed for detecting prawn and pork freshness reduction in real-time via discernible colour transition, suggesting its extensive promise for smart packaging applications.