Selective synthesis of fluorescent metal nanoclusters over metal nanoparticles

Metal nanoparticles and nanoclusters are pivotal in nanomaterial science, each offering unique properties for diverse applications. Nanoclusters, typically smaller than 2 nm, exhibit distinct optical and electronic characteristics due to quantum confinement, resulting in fluorescence emission. In contrast, metal nanoparticles, sized between 2 and 100 nm, exhibit absorption spectra. Both are synthesized by reducing metal precursors in the presence of a suitable stabilizing agent. While nanoparticles have been the historical research focus, recent attention has shifted to nanoclusters for their exceptional properties and their synthesis has evolved significantly over the past few decades. This review discusses the selective synthesis of nanoclusters over nanoparticles, emphasizing the role of various factors such as ligand concentration (metal-to-ligand ratio), reducing agents, pH, reaction time and temperature, solvents, and assistant reagents. Higher ligand concentrations stabilize smaller nanoclusters by preventing aggregation, while lower concentrations lead to larger nanoparticles. Stronger reducing agents produce smaller, more uniform particles, whereas weaker reducing agents yield larger ones. pH affects nanocluster size and emission properties. Solvents and assistant reagents influence reaction kinetics and material properties. Temperature and reaction time also play critical roles in controlling nanocluster size and properties. These insights guide the optimized synthesis of metal nanoclusters, for their specific applications.