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Photoluminescence: Applications01:14

Photoluminescence: Applications

Photoluminescence offers a wide range of applications due to its inherent sensitivity and selectivity. This technique allows for both direct and indirect analyses of the analyte. Direct quantitative analysis is possible when the analyte exhibits a favorable quantum yield for fluorescence or phosphorescence. However, an indirect analysis may be feasible if the analyte is not fluorescent or phosphorescent, or if the quantum yield is unfavorable. Indirect methods include reacting the analyte with...

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Synthesis and Characterization of Functionalized Metal-organic Frameworks
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Metal-organic framework-based hybrids with photon upconversion.

Xiaokai Chen1, Xiaodong Zhang1, Yanli Zhao1

  • 1School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, 21 Nanyang link, Singapore, 637371, Singapore. zhaoyanli@ntu.edu.sg.

Chemical Society Reviews
|November 14, 2024
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Summary

This review explores upconverting metal-organic framework (MOF)-based hybrids, which combine the unique properties of upconversion materials (UCMs) and MOFs. These advanced materials show promise for energy, catalysis, and biomedical applications.

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Area of Science:

  • Materials Science
  • Photoluminescence
  • Nanotechnology

Background:

  • Upconversion materials (UCMs) exhibit anti-Stokes emission, making them significant in photoluminescence.
  • Metal-organic frameworks (MOFs) are versatile materials with high porosity, tunable structures, and functional sites.
  • Integrating UCMs with MOFs enhances UCM properties and performance.

Purpose of the Study:

  • To review advancements in upconverting MOF-based hybrids.
  • To cover classifications, luminescence mechanisms, designs, properties, and applications.
  • To analyze the synergistic functions and explore future research directions.

Main Methods:

  • Literature review of upconverting MOF-based hybrid research.
  • Analysis of luminescence mechanisms and material design strategies.
  • Evaluation of applications in energy, catalysis, and biomedical fields.

Main Results:

  • Upconverting MOF-based hybrids successfully integrate UCMs and MOFs.
  • Diverse designs and properties of these hybrids are presented.
  • Significant potential in energy, catalysis, and biomedical applications is demonstrated.

Conclusions:

  • Upconverting MOF-based hybrids represent a promising class of advanced materials.
  • Further research can optimize properties, performance, and expand applications.
  • This review provides a comprehensive overview and future outlook for the field.