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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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B(C6F5)3 Co-Catalyst Promotes Unconventional Halide Abstraction from Grubbs I to Enhance Reactivity and Limit

Austin W Medley1, Diya Patel1, Calvin Utne1

  • 1Department of Chemistry and Biochemistry, Old Dominion University, 4501 Elkhorn Avenue, Norfolk, Virginia 23529, United States.

Organometallics
|November 15, 2024
PubMed
Summary

Adding tris(pentafluorophenyl)borane Lewis acid enhances Grubbs I catalyst reactivity for ring-opening metathesis polymerization. This cost-effective method achieves divergent products via halide abstraction, not phosphine dissociation.

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