Visible Light Induced Photocatalytic Degradation of Diclofenac in Aqueous Solution Using Fabricated ZnO/g-C₃N₄ by Facile Calcination Technique

The ability of the heterojunction between two distinct semiconductors with appropriately matched band gaps to improve the separation of photogenerated electron-hole pairs has been demonstrated to enhance photocatalytic activity. Hence, ZnO/g-C₃N₄ composites have been fabricated by the facile deposition and calcination of ZnO and g-C₃N₄. X-ray photoelectron spectroscopy, powder X-ray diffraction, and Fourier transform infrared spectroscopy confirm the formation of the composite. Scanning electron microscope, transmission electron microscope, and energy-dispersive X-ray spectroscopy morphological analysis reveal that ZnO was homogeneously spread over the g-C₃N₄ surface. UV-vis diffuse reflectance spectroscopy analysis shows the slightly enhanced visible light absorption ability of the composite. Photoluminescence (PL) spectroscopy and electrochemical impedance spectroscopy analysis prove the higher charge separation of the composite during the irradiation of light. The composite shows admirable photocatalytic efficiency in the visible light-driven photocatalytic degradation of an aqueous diclofenac (DFC) solution. The superoxide anion radical (•O₂ ^-) and hydroxyl radical (•OH) act as reactive species during the degradation reaction. Probable reaction mechanisms have been proposed.