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Updated: Jun 7, 2025
Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
Published on: April 10, 2018
Strategies for Achieving Carbon Neutrality: Dual-Atom Catalysts in Focus
Yuting Liu1, Yurui Qing1, Wenhai Jiang1
1College of Geography and Environmental Sciences, Zhejiang Normal University, Jinhua, 321004, China.
Abstract:
Carbon neutrality is a fundamental strategy for achieving the sustainable development of human society. Catalyzing CO2 reduction into various high-value-added fuels serves as an effective pathway to achieve this strategic objective. Atom-dispersed catalysts have received extensive attention due to their maximum atomic utilization, high catalytic selectivity, and exceptional catalytic performance. Dual-atom catalysts (DACs), as an extension of single-atom catalysts (SACs), not only retain the advantages of SACs, but also produce many new properties. This review initiates its exploration by elucidating the mechanism of CO2 reduction reaction (CO2RR) from CO2 adsorption and CO2 activation. Then, a comprehensive summary of recently developed preparation methods of DACs is presented. Importantly, the mechanisms underlying the promoted catalytic performance of DACs in comparison to SACs are subjected to a comprehensive analysis from adjustable adsorption capacity, tunable electronic structure, strong synergistic effect, and enhanced spacing effect, elucidating their respective superiorities in CO2RR. Subsequently, the application of DACs in CO2RR is discussed in detail. Conclusively, the prospective trajectories and inherent challenges of CO2RR are expounded upon concerning the continued advancement of DACs. This thorough review not only enhances the comprehension of DACs within CO2RR but also accentuates the prospective developments in the design of sophisticated catalytic materials.
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