Strengths and weaknesses of elimination voltammetry with linear scan

Electrochemical methods have undergone many important developments initiated by efforts to increase the sensitivity, selectivity, and stability (S&S&S) and to understand the underlying electrode processes. To meet these goals, there are hardware solutions with applications of new technologies and materials, and software solutions utilizing existing instrumentation. The article presents a viable, easy-to-implement software solution to the main shortcomings of linear sweep voltammetry (low sensitivity, high share of the capacitive component of the current, and the problem of overlapping signals) in the form of elimination voltammetry with a linear scan (EVLS). Based on the different dependences of the individual currents that make up the total voltammetric current (diffusion, charging, kinetics, and various irreversible components) on the scan rate, EVLS can eliminate or preserve particular current components. Increased sensitivity and selectivity can be expected especially in the case of a fully adsorbed electroactive particle subjected to an irreversible electrode process when the elimination of kinetic and capacitive current while preserving the diffusion current provides a theoretically confirmed peak-counter peak signal. EVLS is applicable for testing changes in the polarized electrode/electrolyte interface using EVLS functions eliminating the diffusion component of the current and preserving the kinetic and capacitive currents, which should ensure zero current conduction for a purely diffusion-controlled Nernstian-type reversible process. We point out the strengths, opportunities, and weaknesses of EVLS. Nevertheless, EVLS offers a new tool that contributes to a better understanding of electrochemical processes and their mechanisms.