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Related Concept Videos

Catalysis02:50

Catalysis

26.7K
The presence of a catalyst affects the rate of a chemical reaction. A catalyst is a substance that can increase the reaction rate without being consumed during the process. A basic comprehension of a catalysts’ role during chemical reactions can be understood from the concept of reaction mechanisms and energy diagrams.
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Carbon-dioxide Fixation01:28

Carbon-dioxide Fixation

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Carbon dioxide fixation in prokaryotes enables the assimilation of inorganic carbon into organic molecules, supporting biosynthetic pathways, sustaining ecosystems, and contributing to the global carbon cycle. It also has industrial applications in carbon capture and bioproduct synthesis. Autotrophic organisms rely on this process to utilize CO₂ as a carbon source in diverse environments.The Calvin CycleThe Calvin cycle is the most widespread carbon fixation mechanism, primarily used by...
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Reduction of Alkenes: Catalytic Hydrogenation02:13

Reduction of Alkenes: Catalytic Hydrogenation

11.8K
Alkenes undergo reduction by the addition of molecular hydrogen to give alkanes. Because the process generally occurs in the presence of a transition-metal catalyst, the reaction is called catalytic hydrogenation.
Metals like palladium, platinum, and nickel are commonly used in their solid forms — fine powder on an inert surface. As these catalysts remain insoluble in the reaction mixture, they are referred to as heterogeneous catalysts.
The hydrogenation process takes place on the...
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Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation01:28

Reduction of Benzene to Cyclohexane: Catalytic Hydrogenation

4.3K
Unlike the easy catalytic hydrogenation of an alkene double bond, hydrogenation of a benzene double bond under similar reaction conditions does not take place easily. For example, in the reduction of stilbene, the benzene ring remains unaffected while the alkene bond gets reduced. Hydrogenation of an alkene double bond is exothermic and a favorable process. In contrast, to hydrogenate the first unsaturated bond of benzene, an energy input is needed; that is, the process is endothermic. This is...
4.3K
Reduction of Alkenes: Asymmetric Catalytic Hydrogenation02:17

Reduction of Alkenes: Asymmetric Catalytic Hydrogenation

3.2K
Catalytic hydrogenation of alkenes is a transition-metal catalyzed reduction of the double bond using molecular hydrogen to give alkanes. The mode of hydrogen addition follows syn stereochemistry.
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
3.2K
Products of the Citric Acid Cycle00:53

Products of the Citric Acid Cycle

98.3K
The cells of most organisms—including plants and animals—obtain usable energy through aerobic respiration, the oxygen-requiring version of cellular respiration. Aerobic respiration consists of four major stages: glycolysis, pyruvate oxidation, the citric acid cycle, and oxidative phosphorylation. The third major stage, the citric acid cycle, is also known as the Krebs cycle or tricarboxylic acid (TCA) cycle.
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Related Experiment Video

Updated: Jun 7, 2025

Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy
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Versatile CO2 Transformations into Complex Products: A One-pot Two-step Strategy

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Cascade Catalytic Systems for Converting CO2 into C2+ Products.

Qiaochu Shi1, Boyu Zhang1, Zhenhua Wu1

  • 1School of Environmental Science & Engineering, Tianjin University, Tianjin, 300072, China.

Chemsuschem
|November 20, 2024
PubMed
Summary

Cascade catalysis efficiently converts stable carbon dioxide (CO2) into valuable multi-carbon (C2+) products. This approach lowers energy demands and offers a promising route for carbon neutrality and chemical recycling.

Keywords:
C2+Product synthesisCO2conversionCarbon neutrality and recyclingCascade catalysisC−C Coupling

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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction
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Synthesis and Performance Characterizations of Transition Metal Single Atom Catalyst for Electrochemical CO2 Reduction

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Laboratory Production of Biofuels and Biochemicals from a Rapeseed Oil through Catalytic Cracking Conversion
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Laboratory Production of Biofuels and Biochemicals from a Rapeseed Oil through Catalytic Cracking Conversion
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Area of Science:

  • Catalysis
  • Green Chemistry
  • Carbon Capture and Utilization

Background:

  • Excessive carbon dioxide (CO2) emissions cause significant environmental issues.
  • CO2 is a renewable, abundant C1 carbon source for chemical synthesis.
  • Converting CO2 into higher-value multi-carbon (C2+) products is challenging due to its stability and the energy required for C-C coupling.

Purpose of the Study:

  • To review advancements in cascade catalytic systems for synthesizing C2+ products from CO2.
  • To highlight the advantages and synergistic effects in cascade catalysis for CO2 conversion.
  • To provide a framework for efficient CO2 utilization and next-generation catalyst development.

Main Methods:

  • Exploration of cascade catalytic strategies for CO2 conversion.
  • Analysis of synergistic effects among active sites in catalytic systems.
  • Examination of reaction mechanisms for CO2 to C2+ product synthesis.

Main Results:

  • Cascade catalysis effectively overcomes the stability and energy barriers in CO2 conversion.
  • Coordinated active components and intermediate transfers facilitate efficient C-C coupling.
  • Significant progress has been made in synthesizing C2+ products from CO2 using cascade systems.

Conclusions:

  • Cascade catalysis offers a promising pathway for achieving carbon neutrality and chemical recycling.
  • This approach enables the conversion of CO2 into higher-value C2+ products with reduced energy consumption.
  • Future research should focus on optimizing cascade systems for industrial-scale CO2 utilization.