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Single parameter aging and density scaling.

Tina Hecksher1, Kristine Niss1

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The single-parameter aging (SPA) ansatz accurately predicts experimental data for temperature down-jumps, even large ones. This study validates SPA and explores density scaling for out-of-equilibrium systems.

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Area of Science:

  • Condensed matter physics
  • Physical chemistry
  • Statistical mechanics

Background:

  • Previous studies on temperature down-jumps in out-of-equilibrium systems faced challenges predicting large temperature changes.
  • The single-parameter aging (SPA) ansatz and density scaling were previously applied with limited success for large temperature jumps.

Purpose of the Study:

  • To re-evaluate the applicability of the SPA ansatz to experimental temperature down-jump data.
  • To demonstrate the effectiveness of the original SPA ansatz for all tested temperature ranges.
  • To discuss extensions of density scaling concepts for out-of-equilibrium systems.

Main Methods:

  • Analysis of experimental data from Di Lisio et al. (2023) concerning temperature down-jumps.
  • Application of the single-parameter aging (SPA) ansatz in its original formulation.
  • Exploration of density scaling principles in non-equilibrium conditions.

Main Results:

  • The SPA ansatz successfully predicted experimental data across all tested temperature down-jumps, including large jumps (ΔT > 20 K).
  • The original SPA formulation proved robust for analyzing the out-of-equilibrium dynamics.
  • Different theoretical approaches for extending density scaling were considered.

Conclusions:

  • The SPA ansatz is a valid and effective tool for analyzing temperature down-jumps in out-of-equilibrium systems.
  • The study provides a foundation for further theoretical development in density scaling for non-equilibrium phenomena.
  • Accurate prediction of dynamics in complex systems is achievable with refined theoretical models.