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Updated: Jun 7, 2025

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Proton hyperfine couplings and Overhauser DNP.

Michael Mardini1, Christy George1, Ravi Shankar Palani1

  • 1Department of Chemistry and Francis Bitter Magnet Laboratory, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.

Journal of Magnetic Resonance (San Diego, Calif. : 1997)
|November 20, 2024
PubMed
Summary

New trityl radicals were studied for dynamic nuclear polarization (DNP). Researchers found that large hyperfine couplings alone do not guarantee Overhauser effect DNP, highlighting the importance of electron spin distribution.

Keywords:
DNPEPRHyperfine couplingsNMRTrityl

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