Enhanced fluoride extraction from contaminated soil combining chelator and surfactant: Insights into adsorptive...

Biodegradable chelators and surfactants are promising alternatives to conventional washing agents for remediating soil contaminated with toxic elements, owing to their excellent extractability and environmental compatibility. Most previous studies have primarily aimed at maximizing removal efficiency. However, understanding their underlying extraction mechanism is essential to expand the application potential of chelator- or surfactant-assisted washing systems. This study evaluated the effectiveness of chelators and surfactants in remediating fluoride (F)-contaminated soil and explored their associated extraction mechanisms. Our findings highlight a biodegradable chelator, HIDS (3-hydroxy-2,2'-imino disuccinic acid) as uniquely effective in F extraction with minimal F-bearing minerals dissolution (Ca, Fe, and Al). Chelator recovery rates and zeta potential measurements in post-washed solutions suggests that HIDS adsorbs onto soil surfaces, displacing the originally adsorbed F and enhancing the negative surface charge to inhibit F re-adsorption. Additionally, applying an anionic surfactant to enhance F extraction from soil showed promising results. Notably, a binary blend of HIDS and in-lab designed anionic surfactant, SDT (sodium N-dodecanoyl-taurinate), achieved the highest F removal rate (132 mg kg^-1) under optimized washing conditions (HIDS: 10 mmol L^-1, SDT: 10 mmol L^-1, solution pH: 3, and washing time: 1 h), enhancing F extraction by 22% compared to HIDS-only washing (108 mg kg^-1; washing time: 3 h). The FT-IR and zeta potential measurements suggested that SDT adsorbed onto the soil surface. The action of the HIDS-SDT blend towards F extraction involves the complexation and acid dissolution of F-bearing soil minerals, followed by F replacement through chelator and surfactant adsorption. This process mitigated F back-adsorption and enhanced F extraction by generating a negatively charged soil surface.