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Updated: Jun 6, 2025

Methods of Ex Situ and In Situ Investigations of Structural Transformations: The Case of Crystallization of Metallic Glasses
Published on: June 7, 2018
Simple Fluctuations in Simple Glass Formers
Corentin C L Laudicina1, Patrick Charbonneau2,3, Yi Hu2
1Soft Matter and Biological Physics, Department of Applied Physics, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Abstract:
Critical single-particle fluctuations associated with particle displacements are inherent to simple glass-forming liquids in the limit of large dimensions and leave a pseudocritical trace across all finite dimensions. This characteristic could serve as a crucial test for distinguishing between theories of glass formation. We here examine these critical fluctuations, as captured by the well-established non-Gaussian parameter, within both mode-coupling theory (MCT) and dynamical mean-field theory (DMFT) across dimensions for hard sphere fluids and for the minimally structured Mari-Kurchan model. We establish general scaling laws relevant to any liquid dynamics theory in large dimensions and show that the dimensional scalings predicted by MCT are inconsistent with those from DMFT. Simulation results for hard sphere fluids in moderately high dimensions align with the DMFT scenario, reinforcing the relevance of mean-field theory for capturing glass physics in finite dimensions. We identify potential adjustments to MCT to account for certain mean-field physics. Our findings also highlight that local structure and spatial dimensionality can affect single-particle critical fluctuations in nontrivial ways.
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