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Adding Mandarin Peel Waste to a Biodegradable Polymeric Matrix: Reinforcement or Degradation Effect?
Vincenzo Titone1, Maria Chiara Mistretta1,2, Luigi Botta1,2
1INSTM Research Unit, Department of Engineering, University of Palermo, V. le delle Scienze, 90128 Palermo, Italy.
Polymers
|November 27, 2024
Summary
This study explores using fruit and vegetable waste as fillers in biodegradable materials. While increasing stiffness, the waste fillers decreased tensile strength due to poor adhesion and degradation.
Area of Science:
- Materials Science
- Sustainable Engineering
- Waste Valorization
Background:
- Fruit and vegetable waste presents a significant disposal challenge.
- Utilizing waste streams for material production aligns with circular economy principles.
- Biodegradable composites offer environmentally friendly alternatives to conventional plastics.
Purpose of the Study:
- To investigate the incorporation of an endemic fruit and vegetable waste into a biodegradable matrix.
- To characterize the mechanical, rheological, and morphological properties of the resulting biocomposites.
- To understand the relationship between filler content, processability, structure, and material properties.
Main Methods:
- Preparation of biocomposites with varying filler concentrations.
- Mechanical testing (elastic modulus, tensile strength, elongation at break).
- Rheological and morphological characterization.
Main Results:
- Biocomposite stiffness increased by up to 27% in elastic modulus with filler addition.
- Tensile strength decreased by approximately 50% and elongation at break reduced to about 7% at highest filler content.
- Poor interfacial adhesion and filler-induced degradation (due to citric acid/impurities) were identified as key factors.
Conclusions:
- The studied endemic waste can be incorporated into biodegradable matrices, enhancing stiffness.
- Challenges in interfacial adhesion and degradation limit tensile properties.
- Further research is needed to optimize filler treatment and improve composite performance for sustainable applications.

