Efficient electrocatalysis conversion of glycerol to formate in alkaline solution by nickel (oxy)hydroxide supported...

Electrochemical oxidation of glycerol into value-added chemicals represents a sustainable approach for not only valorizing biomass resources but also improving the energy efficiency of electrolysis by replacing the kinetically sluggish oxidation of water at the anode. Here, we present a nickel (oxy)hydroxide supported cobalt nanoneedle arrays catalyst (CoNA-NiOH/NF-2) for effective oxidation of glycerol. The loaded Co(OH)₂ forms more oxygen defects, increases the active sites, and enhances the performance of glycerol oxidation. The CoNA-NiOH/NF-2 catalyst significantly reduces energy consumption by achieving a current density of 10 mA cm^-2 at a low voltage of 1.22 V vs. RHE, and 100 mA cm^-2 at 1.42 V vs. RHE, which is approximately 240 mV lower than oxygen evolution reaction (OER). Additionally, the Faraday efficiency of formate generation reached 98 %. The growth of renewable energy sources will greatly benefit from this strategy, which calls for replacing anodic OER with biomass oxidation.