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Robust and Versatile Biodegradable Unclonable Anti-Counterfeiting Labels with Multi-Mode Optical Encoding Using
Ziting Wang1, Meng Li2, Yinghao Fu1
1National Laboratory of Solid State Microstructures, Key Laboratory of Intelligent Optical Sensing and Manipulation, College of Engineering and Applied Sciences, and Collaborative Innovation Center of Advanced Microstructures, Nanjing University, Nanjing, 210023, China.
Advanced Materials (Deerfield Beach, Fla.)
|December 3, 2024
Summary
This study introduces novel, all-biomaterial anti-counterfeiting labels using silk and calcite. These labels offer secure, unclonable authentication with high encoding capacity for advanced information security.
Area of Science:
- Materials Science
- Biotechnology
- Information Security
Background:
- Physical unclonable functions (PUFs) are crucial for security but often lack sustainability.
- Existing PUF platforms face challenges in balancing encoding capacity, encryption diversity, and biocompatibility.
- There is a need for eco-friendly and biocompatible PUF solutions for anti-counterfeiting applications.
Purpose of the Study:
- To develop sustainable, all-biomaterial-based unclonable anti-counterfeiting labels.
- To achieve multi-mode encoding, multi-level cryptographic keys, and multiple authentication operations.
- To integrate biocompatible materials for enhanced safety and reduced environmental impact.
Main Methods:
- Utilized biomimetic-grown calcites imprinted on silk protein films for inherent non-clonability.
- Embedded photoluminescent molecules into calcite lattices for fluorescence and birefringence encoding.
- Developed authentication methods using Hamming distance, convolutional neural networks, and angle-dependent polarization.
Main Results:
- Created labels with randomized calcite characteristics mediated by silk protein for unclonability.
- Achieved high-capacity encoding via fluorescence patterns and birefringence.
- Enabled multi-level key generation through polarization and multi-channel keys via fluorescence.
- Demonstrated easy and rapid authentication using standard cameras and portable microscopes.
Conclusions:
- The developed anti-counterfeiting labels offer a practical, high-security solution combining biodegradability, green manufacturing, and versatility.
- The platform provides a robust, low-cost, and patternable approach to combat counterfeiting.
- This work advances the integration of biocompatible materials in physical unclonable functions for enhanced information security.

