Atomically Dispersed Mn-Doped Ru@RuO2 Core/Shell Nanostructure with High Acidic Water Oxidation Performance Arising
Haibin Ma1, Jun Zhou2, Yang Zhao3
1Shanghai Key Laboratory for R&D and Application of Metallic Functional Materials, Institute of New Energy for Vehicles, School of Materials Science and Engineering, Tongji University, Shanghai, 201804, P. R. China.
Abstract:
The high overpotential and unsatisfactory stability of RuO2-based catalysts seriously hinder their application in acidic oxygen evolution reaction (OER). Herein, a Ru@RuO2 core/shell catalyst doped with atomically dispersed Mn species, denoted as Ru@Mn-RuO2, is reported, which is prepared by a facile one-pot method. Detailed structural characterizations confirm that Mn is homogeneously and atomically distributed in RuO2 shell, which causes lattice contraction of RuO2. The as-prepared Ru@Mn-RuO2 exhibits a very low overpotential of 190 mV at the current density of 10 mA cm-2 and an excellent stability of 360 h, far surpassing the control samples Ru@RuO2 without atomically dispersed Mn dopants and home-made RuO2 nanoparticles without metallic Ru core. With the further assistance of density functional theory calculations, the enhanced OER activity of Ru@Mn-RuO2 is attributed to multiple synergistic effects, including the MnOx-Ru (oxide shell) synergy, MnOx-Ru (metal core) synergy, and the Ru (core)-RuO2 (shell) synergy. Besides, the atomically dispersed Mn doping can increase the formation energy of soluble Ru cations, thus leading to the excellent stability of the Ru@Mn-RuO2 catalyst. This work shines light on the design of electrocatalysts with multiple synergistic effects towards efficient acid water splitting.
