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Related Concept Videos

2° Amines to N-Nitrosamines: Reaction with NaNO201:20

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Secondary amines react with nitrous acid to form N-nitrosamines, as depicted in Figure 1. Nitrous acid, a weak and unstable acid, is formed in situ from an aqueous solution of sodium nitrite and strong acids, such as hydrochloric acid or sulfuric acid, in cold conditions. In the presence of an acid, the nitrous acid gets protonated. The subsequent loss of water results in the formation of the electrophile known as nitrosonium ion.
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Being able to calculate equilibrium concentrations is essential to many areas of science and technology—for example, in the formulation and dosing of pharmaceutical products. After a drug is ingested or injected, it is typically involved in several chemical equilibria that affect its ultimate concentration in the body system of interest. Knowledge of the quantitative aspects of these equilibria is required to compute a dosage amount that will solicit the desired therapeutic effect.
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An acid-base reaction is one in which a hydrogen ion, H+, is transferred from one chemical species to another. Such reactions are of central importance to numerous natural and technological processes, ranging from the chemical transformations within cells or lakes and oceans to the industrial-scale production of fertilizers, pharmaceuticals, and other substances essential to the society.
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Calibrated Passive Sampling - Multi-plot Field Measurements of NH3 Emissions with a Combination of Dynamic Tube Method and Passive Samplers
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Preconditions for Including the Effects of Urease and Nitrification Inhibitors in Emission Inventories.

Nicholas J Hutchings1, Søren O Petersen2, Karl G Richards3

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Global Change Biology
|December 6, 2024
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Summary
This summary is machine-generated.

Urease and nitrification inhibitors reduce emissions, but real-world conditions are key. We outline criteria for including their proven effects in regulatory emission inventories.

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Area of Science:

  • Agricultural science
  • Environmental science
  • Soil science

Background:

  • Ammonia and greenhouse gas emissions from agricultural sources are significant environmental concerns.
  • Urease and nitrification inhibitors offer a potential solution to mitigate these emissions from fertilizers and manure.
  • The effectiveness of these inhibitors is highly dependent on environmental and application conditions.

Purpose of the Study:

  • To establish criteria for assessing the real-world effectiveness of urease and nitrification inhibitors.
  • To ensure the credibility of emission reduction data used in regulatory emission inventories.
  • To guide the inclusion of inhibitor effects in official environmental reporting.

Main Methods:

  • Reviewing existing scientific literature on inhibitor efficacy under various conditions.
  • Defining specific, measurable criteria for field-based performance validation.
  • Proposing a framework for evaluating inhibitor performance relevant to regulatory standards.

Main Results:

  • Effectiveness of inhibitors varies significantly based on soil type, climate, and application methods.
  • Laboratory results do not always translate to real-world emission reductions.
  • A standardized, evidence-based approach is needed for regulatory acceptance.

Conclusions:

  • Regulatory emission inventories must incorporate inhibitor effects validated under real-world agricultural conditions.
  • Clear, evidence-based criteria are essential for the reliable assessment of inhibitor performance.
  • Adoption of these criteria will enhance the accuracy and credibility of environmental reporting on agricultural emissions.